Why
Ni+2 paramagnetic whereas Zn+2 diamagnetic?
Para
magnetism and diamagnetism of a substance depends on the number of electrons
occupied by it. A paramagnetic substance is one that contains one or more
unpaired electrons.
On
the other hand, a diamagnetism substance is one that does not contain any odd
electrons. Now,
Ni +2 ion is 3d8 system. According to Hund’s rule the
outer electronic configuration of Ni+2 ions is [Ar] 3d8.
From
electronic configuration of Ni +2 ion, it has been found that it has
two unpaired electrons.
Now,
depending upon the hybridization, there are two types of possible structure of
Ni +2 ion are formed with co-ordination number 4.
If
the complex involves ‘sp3’ hybridization, it would have tetrahedral structure.
Again, if the complex involves ‘dsp2’ hybridization, it would have squareplanar structure.